Japanese Correspondence
Yamada Science Foundation
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Progress Report of YSF Supported Science Program


Summary of Research Projects (Suppots in 2001 Fiscal Year)
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Subjects Novel Phase Transitions in Ferroelectric Compounds with Linear-Chain Substructure
Representative researcher Chiba University Tetsuya KATO
Joint researcher Tokyo Institute of Technology Katsunori IIO
Tokyo Institute of Technology Hidekazu TANAKA
Teikyo University Toshiharu MITSUI
Experimental studies of successive structural phase transitions of KNiCl3 and related crystals (KNiCl3-family crystals) RbMnBr3, TlFeCl3, TlCoCl3, RbFeBr3, RbCoBr3 and RbVBr3 with dielectric and diffraction methods were summarized. Their prototype structure is the CsNiCl3-type structure, which is known to contain NiCl3 linear-chain substructure. Some phases of GroupsI(KNiCl3, RbMnBr3, TlFeCl3 and TlCoCl3) , II(RbFeBr3) and III(RbCoBr3 and RbVBr3) crystals were shown to be ferroelectric with spontaneous polarization parallel to the chain (c-axis). Transition points and space group symmetries of each phase were listed. It was discussed that those structural phase transitions can be attributed to competition between the distortion of NiCl6 octahedra which are directly connected to the spontaneous polarization and that of KCl12 polyhedra which might be closely related to the softening of vibrational K4-mode. The reasons why some crystals with the CsNiCl3-type structure (such as RbNiBr3) does not undergo such structural phase transitions and why the spontaneous polarization of Group I KNiCl3-family crystals disappears in phase V remain unsolved.