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Yamada Science Foundation
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Subjects Dynamic Structural Control and Recognition of a Chiral Binaphthyl Group
Representative researcher The University of Tokyo Kyoko NOZAKI
Joint researcher The University of Tokyo Koji NAKANO
Using palladium-catalyzed double N-arylation strategy, 2,2'-di(carbazol-9-yl)- 1,1'-binaphthyl [(S)-1a] has been successfully synthesized. Upon photo-irradiation, electron transfer from the carbazole ring to the naphthalene ring took place in compound (S)-1a to induce an excimer formation, as was evidenced by circular dichroism (CD) and circular polarized luminescence (CPL) measurement.