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Summary of Research Projects (Supports in 2003
Fiscal Year)
| Subjects |
Dynamic Structural Control and Recognition of a Chiral Binaphthyl Group |
| Representative researcher |
The University of Tokyo Kyoko NOZAKI |
| Joint researcher |
The University of Tokyo Koji NAKANO |
| Using palladium-catalyzed
double N-arylation strategy, 2,2'-di(carbazol-9-yl)- 1,1'-binaphthyl
[(S)-1a] has been successfully synthesized. Upon photo-irradiation,
electron transfer from the carbazole ring to the naphthalene
ring took place in compound (S)-1a to induce an excimer formation,
as was evidenced by circular dichroism (CD) and circular
polarized luminescence (CPL) measurement. |
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