|
Summary of Research Projects (Supports in 2005
Fiscal Year)
| Subjects |
Development of an Efficient Catalytic Method for the
Synthesis of Supramolecules |
Representative
researcher |
Tokyo University of Science Shinichi SAITO
|
| We developed a new and efficient method
for the synthesis of [2]rotaxanes. Thus, [2]rotaxanes were synthesized
by the reactions catalyzed by a macrocyclic Cu(I)-phenanthroline complex.
The catalytic moiety of the ring component was located inside the ring
so that the rotaxanes could be prepared efficiently. A C-S bond forming
reaction and oxidative dimerization of alkyne were utilized. |
|
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